Web(3) Locate system point, pH = pK and HA = A-; note that the cross over is 0.3 log units below the CT line, for the acetic acid above this is at pH 4.7 (4) Draw lines for the species, slope = +1 for [A-] and slope = -1 for [HA]; remember that at a pH lower than the system point HA >A-, at a pH higher than the system point A->HA WebCT 13 C a R b R c R R (9.2) and conversely, inserting the proper fractionation factors as mentioned before: T b a b c C R R a/b c/b C 13 T b 13 (9.3) The next sections will be devoted to analysing the chemical composition of carbonate waters. 9.2 CARBONIC ACID EQUILIBRIA In the presence of gaseous CO2, dissolved CO2 exchanges with CO2 gas:
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